2-Chloro-N′-(5-hydroxy-2-nitrobenzylidene)benzohydrazide

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منابع مشابه

[5-Chloro-2-hydroxy-N′-(2-oxido­ben­zyl­idene)benzo­hy­dra­zidato]­pyridine­copper(II)

In the title complex, [Cu(C(14)H(9)ClN(2)O(3))(C(5)H(5)N)], the Cu(II) ion exhibits a distorted trans-CuN(2)O(2) square-planar geometry arising from the O,O,N-tridentate ligand and a pyridine mol-ecule. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal structure, weak inter-molecular C-H⋯π inter-actions generate a chain. The crystal studied was an inversion twin.

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In the title compound, C(11)H(12)ClNO(3), the conformation of the N-H bond in the amide segment is syn with respect to the ortho-Cl atom. The amide and carboxyl C=O groups are syn to each other. Furthermore, the C=O and O-H bonds of the carboxyl group are in syn positions with respect to each other. The dihedral angle between the benzene ring and the amide group is 47.8 (2)°. In the crystal, mo...

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In the title compound, C(13)H(12)ClNO(3)S, the dihedral angle between the two aromatic rings is 73.94 (9)°. An intra-molecular C-H⋯O hydrogen bond occurs. In the crystal, inter-molecular N-H⋯O hydrogen bonds connect the mol-ecules to centrosymmetric dimers, forming an R(2) (2)(8) ring motif. The packing is consolidated by C-H⋯O hydrogen bonds and weak π-π inter-actions [centroid-centroid distan...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810001303